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KMID : 0903519940370030216
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Journal of the Korean Society of Agricultural Chemistry and Biotechnology
1994 Volume.37 No. 3 p.216 ~ p.220
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Synthesis of Anisyltitanium Compounds and their Reactivity
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Abstract
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Organoanisyltitanium compounds which have chlorine or isopropoxy group as ligand were synthesized and purely isolated. These new compounds were proved to be stable at 0℃ under argon atmosphere for some weeks. They react readily at low temperature with carbonyl compound, especially aldehyde and ketone, to coresponding alcohols. In competition reaction of aldehyde/ketone pair these organotitanium species showed complete aldehyde selectivity.
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